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Agrivoltaic systems, which achieve sustainable food and energy co-production (SFE) by installing photovoltaics (PVs) on farmland, offer a climate-resilient solution for meeting ”full Earth” needs while adhering to land limitations. However, limited research on major row crops, such as corn (Zea Mays), constrains the widespread adoption of agrivoltaics. To bridge this research gap, a two-step process was executed. First, extensive corn growth data was collected from neighboring regions, specifically segregating ”with-PV” (shaded) and ”without-PV” (unshaded) areas under real farming conditions. Using data from unshaded areas, the APSIM plant model was calibrated. Subsequently, an analytical shadow model was used to compute the spatiotemporal shadow distribution (SSD) for each row of corn between PV panels. This SSD data helped validate the APSIM model using the experimental corn yield data from shaded areas.more » « less
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Ultra-thin sputter-deposited infrared rugate mirror for enhancing solar-to-thermal energy conversionA dielectric mirror with high infrared reflection and high visible transmission, based on an easily fabricated stepped index rugate filter structure, is presented. Its fabrication involves sputtering depositions, using only two targets, to make five different material compositions. The ultra-wide reflection band is tunable in both position and width, adapting the thickness of the layers and eventually introducing chirped layers. When applied to evacuated solar thermal devices, efficiency improvements of up to 30% can be achieved, making this mirror an attractive solution for reducing radiative losses through the cold-side photon recycling mechanism.more » « less
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Abstract — Photoluminescence Excitation Spectroscopy (PLE) is a contactless characterization technique to quantify Shockley-Reed-Hall (SRH) lifetimes and recombination velocities in direct band gap experimental semiconductor materials and devices. It is also useful as to evaluate surface passivation and intermediate fabrication processes, since it can be implemented without the need for development of effective contact technologies. In this paper, we present a novel experimental PLE system for precision-based quantification of the aforementioned parameters as well as a system for which absolute PLE characterization may occur. Absolute PLE measurements can be used to directly calculate VOC for new photovoltaic (PV) material systems and devices. Key system capabilities include a continuous excitation spectrum from 300 nm –1.1 μm, automated characterization, up to 1 nm wavelength resolution (up to 60x higher than prior work), and a reduced ellipsometry requirement for post-processing of data. We utilize a GaAs double heterostructure (DH) and an InP crystalline wafer as calibration standards in comparison with data from an LED-based PLE to demonstrate the validity of the results obtained from this new system. Index Terms – photovoltaic cells, photoluminescence, charge carrier lifetime, gallium arsenide, indium phosphide.more » « less
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Abstract Thermophotovoltaic (TPV) technology converts heat into electricity using thermal radiation. Increasing operating temperature is a highly effective approach to improving the efficiency of TPV systems. However, most reported TPV selective emitters degrade rapidly via. oxidation as operating temperatures increase. To address this issue, replacing nanostructured oxide‐metal films with oxide–oxide films is a promising way to greatly limit oxidation, even under high‐temperature conditions. This study introduces new all‐oxide photonic crystal designs for high‐temperature stable TPV systems, overcoming limitations of metal phases and offering promising material choices. The designs utilize both yttria‐stabilized zirconia (YSZ)/MgO and CeO2/MgO combinations with a multilayer structure and stable high‐quality growth. Both designsexhibit positive optical dielectric constants with tunable reflectivity, measured via optical characterization. Thermal stability testing using in situ heating X‐ray diffraction (XRD) suggests high‐temperature stability (up to 1000 °C) of both YSZ/MgO and CeO2/MgO systems. The results demonstrate a new and promising approach to improve the high‐temperature stability of TPV systems, which can be extended to a wide range of material selection and potential designs.more » « less
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